- PbTiO$_3$첨가에 의한 BaTiO$_3$의 입계이동
- ㆍ 저자명
- 이호용,김재석,강석중
- ㆍ 간행물명
- 요업학회지
- ㆍ 권/호정보
- 1999년|36권 4호|pp.354-359 (6 pages)
- ㆍ 발행정보
- 한국세라믹학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
When PbTiO3 particles were scattered on a polished surface of sintered BaTiO3 and annealed at 125$0^{circ}C$ cchemically induced grain boundary migration of BaTiO3 grains occurred near the scattered PbTiO3 particles In some BaTiO3 grain surfaces chemically induced recrystallization was also observed. During the annealing the scattered PbTiO3 particles changed to a (Ba0.6Pb0.4)TiO3 solid solution by diffusion of Ba from the sint-ered BaTiO3. The coherency strain energy of a coherent (Ba0.8Pb0.2)TiO3 layer on BaTiO3 was calculated to be between 1.94 and 3.11 [MJ/m3] depending on crystallographic orientation. The experimental results and calculation showed that the chemically induced grain boundary migration could be induced in BaTiO3 with low elastic constants when the amount of solute alloying was high enough