- ${Li_2}{CO_3}-{Li_3}{PO_4}-{Al_2}{O_3}$계의 고체 전해질 및 ${LiMn_2}{O_4}$의 기준전극을 사용한 $CO_2$ 가스센서
- ㆍ 저자명
- 김동현,윤지영,박희찬,김광호
- ㆍ 간행물명
- 한국세라믹학회지
- ㆍ 권/호정보
- 2000년|37권 8호|pp.817-823 (7 pages)
- ㆍ 발행정보
- 한국세라믹학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
A solid-state electrochemicall cell for sensing CO2 gas was fabricated using a solid electrolyte of Li2CO3-Li3PO4-Al2O3 mixture and a reference electrode of LiMn2O4. The e.m.f. (electromotive force) of sensor showed a good accordance with theoretical Nernst slope (n=2) for CO2 gas concentration range of 100-10000 ppm above 35$0^{circ}C$. The e.m.f. of sensor was constant regardless of oxygen partial pressure at the high temperature above 0.1 atm. It was, however, a little depended on oxygen partial pressure as the pressure decreased below 0.1 atm. The oxygen-dependency of our sensor gradually disappeared as the operating temperature increased. The sensing behavior of our CO2 sensor was affected by the presence of water vapor, but its effect was small comparing with other sensors.