This study describes the effect of γ-ray irradiation on the properties of insulation materials for low voltage cables in a nuclear power plant. The radiation effects were characterized by measuring OIT, FTIR, electrical properties of the irradiated specimens. As a result, they showed the decrease of OIT and the increase of chemical structural defects with the increase of γ-ray amount. Also, the electrical properties such as dielectrical constant, tan $delta$ and current were changed by aging. These changes may come from the increase of chemical structural defects by $delta$-ray irradiation.