The gasoline engine tends to high performance, fuel economy, small-sized. Therefore, it is necessary to solve the problems on thermal load, abnormal combustion, etc, in the engine, Thine film instantaneous temperature measurement probe was made. And the manufactural method of probe was established. The instantaneous surface temperatures in the constant volume combustion chamber were measured by this probe and the heat flux was obtained by Fourier analysis. The authors measured the wall temperature of combustion chamber and computed the heat flux through the cylinder wall in order to understand the combustion characteristics depending on height of probe. For achieving this goal, the thin film instantaneous temperature probe was developed for analyzing the instantaneous surface wall temperature and unsteady heat flux on the constant volume combustion chamber.