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분무열분해법에 의한 구리염화물 용액으로부터 CuO 분말 제조에 관한 연구
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  • 분무열분해법에 의한 구리염화물 용액으로부터 CuO 분말 제조에 관한 연구
저자명
유재근,박희범,Yu. Jae-Geun,Park. Hui-Beom
간행물명
한국재료학회지
권/호정보
2002년|12권 1호|pp.58-67 (10 pages)
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한국재료학회
파일정보
정기간행물|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

In this study copper chloride(CuCl$_2$) solution was used as raw material to produce the fine copper oxide powder which has less than 1 $mu extrm{m}$ average particle size and has uniform particle size distribution by spray pyrolysis process. In the present study, the effects of reaction temperature, the injection speed of solution and air, the nozzle tip size and the concentration of raw material solution on the properties of produced powder were studied. The structure of the powder became much more compact with increasing the reaction temperature regardless of copper concentration of the raw material solution. The particle size of the powder increased accordingly with increasing the reaction temperature in case of 30 g/$ell$ copper concentration of the solution. The particle size of the powder increased accordingly, and the surface structure of the powder became more porous with increasing the copper concentration of the raw material solution. When copper concentration in raw material solution was more than 100 g/$ell$, all produced powder was CuCl regardless of reaction temperatures. When copper concentration in solution was below 30 g/$ell$ and reaction temperature was higher than 90$0^{circ}C$, CuO was the main phase. The surface of the powder tended to become porous with increasing the injection speed of solution. Particle size was increased and the surface of the powder showed severely disrupted state with increasing the nozzle tip size. The particle size was decreased and the particle size distribution was more uniform with increasing the air pressure through the nozzle.