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Experimental Determinations of Coherent Multidimensional Vibrational Spectroscopy
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취소
  • Experimental Determinations of Coherent Multidimensional Vibrational Spectroscopy
  • Experimental Determinations of Coherent Multidimensional Vibrational Spectroscopy
저자명
Besemann. Daniel,Condon. Nicholas,Meyer. Kent,Zhao. Wei,Wright. John C.
간행물명
Bulletin of the Korean Chemical Society
권/호정보
2003년|24권 8호|pp.1119-1125 (7 pages)
발행정보
대한화학회
파일정보
정기간행물|ENG|
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기타
이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
서지반출

기타언어초록

Coherent multidimensional vibrational spectroscopy is a new technique for establishing correlations between features in vibrational spectra that are caused by intra- and intermolecular interactions. These interactions cause cross-peaks between vibrational transitions that reflect the coupling. In this paper, we use Doubly Vibrationally Enhanced Infrared Spectroscopy (DOVE-IR) and DOVE-Raman processes to obtain coherent two dimensional vibrational spectra. The spectra are fitted to obtain the dephasing rates and third order susceptibilities $(χ^{(3)})$ for the nonlinear processes. We show that the DOVE $χ^{(3)}$ values are directly related to the molar absorptivities and Raman $χ^{(3)}$. We then use these relationships to obtain estimates for the $χ^{(3)}$ of the stimulated photon echo and $χ^{(5)}$ of the six wave mixing spectroscopies, respectively. We also predict the ratio of the cascaded four wave mixing signal to the six wave mixing signal.