- 화학기상응축 반응기 내부의 유동해석을 통한 $TiO_2$ 나노분말의 형성과정에 관한 연구
- ㆍ 저자명
- 유지훈,최철진,김용진,김병기,Yu. Ji-Hun,Choe. Cheol-Jin,Kim. Yong-Jin,Kim. Byeong-Gi
- ㆍ 간행물명
- 硏究論文集 : 한국기계연구원
- ㆍ 권/호정보
- 2003년|33권 6호|pp.123-135 (13 pages)
- ㆍ 발행정보
- 한국기계연구원
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
Using the residence time calculated by computer simulation for temperature and gas velocity distribution in CVC reactor, the kinetics on the formation of $TiO_2$ nano powder was analyzed for coagulation process, After abrupt increase of particle size at initial growth stage (< 0.2 $mus$ ), the particle grew in proportion of cubic root to time. The numerically calculated particle sizes well agreed with the experimental results. However, the coarse rutile $TiO_2$ powders having the particle size of over 40 nm were formed on the surface of quratz rod in the reactor. it is thought that the fine anatase particles condensed on quratz rod were sintered in a heated CVC reactor to grow and transform to coarse rutile phase, and the critical size for phase transformation anstase-to-rutile was around 25 nm tn this study.