- SHS합성법에 의한 리튬이온이차전지용 정극활물질 LiMn2O4 의 제조
- ㆍ 저자명
- 장창현,김정한,원창환,Jang. Chang-Hyun,Kim. Jung-Han,Won. Chang-Whan
- ㆍ 간행물명
- 한국세라믹학회지
- ㆍ 권/호정보
- 2005년|42권 7호|pp.503-508 (6 pages)
- ㆍ 발행정보
- 한국세라믹학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
A simple and effective method for the synthesis of LiMn$_{2}$O$_{4}$ powder as a cathode material for lithium secondary battery is reported. Micrometer size LiMn$_{2}$O$_{4}$ was prepared by combustion synthesis technique employing initial mixture of l.l LiNO$_{3}$ -1.3Mn-0.7MnO$_{2}$-1NaCl composition. Parametric study of the combustion process including molar ratio of Mn/MnO$_{2}$ and NaCl concentration were carried out under air atmosphere. The combustion products obtained were additionally heat treated at the temperature 900$^{circ}C$ and the washed by distilled water. The results of charging-discharging characteristics revealed that LiMn$_{2}$O$_{4}$ cell synthesized in the presence of NaCl had a high capacity and much better reversibility than one formed without NaCl An approximate chemical mechanism for LiMn$_{2}$O$_{4}$ formation is proposed.