The increasing use of power electronic equipment in distribution system has been the reason for the greater concern about a harmonic in recent time. Therefore, it is necessary for measurement and modelling to analyze a harmonic level and a transfer characteristic in distribution system. In this paper, the Point of Common Coupling (PCC) is selected to analyze harmonic characteristic of distribution system by IEC 61000-3-6. Harmonic voltage and orient were measured at the PCC of real distribution system Harmonic distribution, nonlinear load component and Total Harmonic Distortion(THD) were verified. The effective and accurate modelling of real distribution system were proved through a analysis of harmonic impedance, voltage and current under steady-state. Harmonic transfer characteristic were investigated through a analysis of harmonic voltage and current under harmonic current source.