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On the Selection of FCC and BCC Lattices in Poly(styrene-b-isoprene) Copolymer Micelles
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  • On the Selection of FCC and BCC Lattices in Poly(styrene-b-isoprene) Copolymer Micelles
  • On the Selection of FCC and BCC Lattices in Poly(styrene-b-isoprene) Copolymer Micelles
저자명
Bang. Joona,Lodge. Timothy P.
간행물명
Macromolecular research
권/호정보
2008년|16권 1호|pp.51-56 (6 pages)
발행정보
한국고분자학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

Spherical micelles of poly(styrene-b-isoprene) (SI) diblock copolymers in selective solvents have been reported to pack onto either face-centered cubic (fcc) or body-centered cubic (bcc) lattices. The selection rule for fcc and bcc lattices has been understood in terms of the intermicellar potentials, and they have been quantified using the ratio of the corona layer thickness to the core radius, $L/R_c$, as suggested by McConnell and Gast. In order to test the validity of the McConnell-Gast criterion, this study compared the $L/R_c$ values from various solutions i.e. nine SI copolymers in several different selective solvents. The McConnell-Gast criterion was not found to be a determining factor, even though it could explain the fcc/bcc selection qualitatively. From the phase diagrams, the transition between fcc and bcc phases was also considered as a function of concentration and temperature, and their physical mechanisms are discussed based on the recent mean-field calculation reported by Grason.