In this work, poly(diallyldimethylammoniumchloride) (PDDAC) and meso-tetrakis(4-carboxyphenyl)porphyrin were considered to produce the self-assembly fabrication films. This method is based on the layer-by-layer (LbL) deposition produced by the electrostatic attraction between positively charged PDDAC and negatively charged porphyrin ions. The result of multilayer fabrication was discussed with the level of color strength (K/S). K/S spectra of the fabricated multilayer films showed gradual increase behaviors. In addition, the color photo images of the fabricated multilayer films showed that PDDAC and porphyrin were successfully attracted by electrostatic self-assembly forces.