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열처리 조건이 PLLA SDY 섬유의 열적 특성 및 물성에 미치는 영향
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  • 열처리 조건이 PLLA SDY 섬유의 열적 특성 및 물성에 미치는 영향
  • Effect of Annealing on the Thermal and Mechanical Properties of PLLA Spin Draw Yarns
저자명
김민섭,김영호,Kim. Min-Sup,Kim. Young-Ho
간행물명
韓國纖維工學會誌
권/호정보
2009년|46권 6호|pp.348-354 (7 pages)
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한국섬유공학회
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

Poly(L-lactic acid) (PLLA) filament fibers were prepared by one-step melt spinning process with spin drawing and the effects of the annealing at $100^{circ}C$ and $120^{circ}C$ on their thermal and mechanical properties were investigated by using a differential scanning calorimeter (DSC), dynamic mechanical analyzer (DMA), and universal testing machine (UTM). The glass transition temperature ($T_g$) of the PLLA spin draw yarn (SDY) fibers increased with increasing annealing time while the melting temperature ($T_m$) remained unaffected. The birefringence increased with increasing time at both $100^{circ}C$ and $120^{circ}C$, indicating the enhanced orientation of the polymers in the fiber. The tenacity of the fibers increased to almost double, while the elongation at break decreased to almost half by 5 minutes annealing at both $100^{circ}C$ and $120^{circ}C$. However, annealing time of more than 5 minutes did not affect the tenacity and elongation at break. The boiling water shrinkage (BWS) decreased continuously with increasing time, the increment was larger for the annealing at $120^{circ}C$ than that at $100^{circ}C$. A BWS of less than 3% was obtained by annealing at $120^{circ}C$ for 30 minutes.