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Decay of Electrical Conductivity in p-Toluene Sulfonate Doped Polypyrrole Films
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  • Decay of Electrical Conductivity in p-Toluene Sulfonate Doped Polypyrrole Films
  • Decay of Electrical Conductivity in p-Toluene Sulfonate Doped Polypyrrole Films
저자명
Kaynak. Akif
간행물명
Fibers and polymers
권/호정보
2009년|10권 5호|pp.590-593 (4 pages)
발행정보
한국섬유공학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

Long term performance of conductivity of p-toluene sulfonic acid (pTSA) doped electrochemically synthesized polypyrrole (PPy) films was estimated from accelerated aging studies between $80^{circ}C$ and $120^{circ}C$. Conductivity decay experiments indicated that overall aging behavior of PPy films deviated from first order kinetics at prolonged aging times at elevated temperatures. However, an approximate value for the activation energy of the conductivity decay of PPy was calculated as E=47.4 kJ/mol, enabling an estimate of a rate constant of k=$8.35 imes10^{-6}$/min at $20^{circ}C$. The rate of decrease of conductivity was not only temperature dependent but also influenced by the dopant concentration. A concentration of 0.005 M pTSA in the electrolyte resulted in a conductive film and when this film was exposed to $120^{circ}C$ for a period of 40 h, the conductivity decayed to about 1/20 of its original value. The concentration of pTSA was increased to 0.05 mol/l and when the resulting film was aged in the same way, it showed a decrease in the conductivity to about 1/3 of its original value. Both microwave transmission and dc conductivity data revealed that highly doped films were considerably more electrically stable than lightly doped films. The dopant had a preserving effect on the electrical properties of PPy.