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Miscibility of Flame Retardant Epoxy Resin with Poly(ethylene terephthalate) and the Characterizations of the Blends
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  • Miscibility of Flame Retardant Epoxy Resin with Poly(ethylene terephthalate) and the Characterizations of the Blends
  • Miscibility of Flame Retardant Epoxy Resin with Poly(ethylene terephthalate) and the Characterizations of the Blends
저자명
Kim. Hwan-Chul,Kim. Dong-Hwan,Park. Jacky,Lim. Jong-Cheol,Park. Young-Wan
간행물명
Fibers and polymers
권/호정보
2009년|10권 5호|pp.594-600 (7 pages)
발행정보
한국섬유공학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

Epoxy resin containing bromine compound was melt blended with PET to obtain flame retardant polymer. The blend product was characterized by DSC, SEM, intrinsic viscosity and melt index measurements. The reaction between the epoxy group of DGEBBA (diglycidyl ether of brominated bisphenol A) and the carboxyl (or hydroxyl) end group of PET led to cross-linking of PET chains, and the intrinsic viscosity and melt index (MI) were increased in the range of equivalent amount of epoxy resin (within 1 %). DSC data revealed that the epoxy resin was not located in the crystalline region but was appeared in the amorphous region of PET matrix. Good miscibility of epoxy resin resulted in the decrease of crystallization temperature and glass transition temperature of PET. The blend was spun into fiber without any problems such as swelling or draw resonance, however, the mechanical properties were decreased as the amount of the DGEBBA was increased.