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Synthesis of Zr-incorporated TiO2 Using a Solvothermal Method and its Photovoltaic Efficiency on Dye-sensitized Solar Cells
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  • Synthesis of Zr-incorporated TiO2 Using a Solvothermal Method and its Photovoltaic Efficiency on Dye-sensitized Solar Cells
  • Synthesis of Zr-incorporated TiO2 Using a Solvothermal Method and its Photovoltaic Efficiency on Dye-sensitized Solar Cells
저자명
Kim. Su-Jung,Kang. Mi-Sook
간행물명
Bulletin of the Korean Chemical Society
권/호정보
2011년|32권 9호|pp.3317-3322 (6 pages)
발행정보
대한화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

This study examines the photoelectric conversion efficiency of dye-sensitized solar cells (DSSCs) when nanometer-sized Zr (0.1, 0.5, and 1.0 mol %)-$TiO_2$ prepared using a solvothermal method is utilized as the working electrode material. The particle sizes observe in the transmission electron microscopy (TEM) images are < 30 nm in all samples. The absorption band is slightly broadened at the tail for the 0.1 mol % Zr-$TiO_2$, and the intensity of the photoluminescence (PL) curves of the Zr-incorporated $TiO_2$ is significantly smaller than that of the pure $TiO_2$. Compared to that using pure $TiO_2$, the energy conversion efficiency is enhanced considerably by the application of Zr-$TiO_2$ in the DSSCs to approximately 6.17% for 0.5 mol % Zr-$TiO_2$ with the N719 dye (10.0 ${mu}m$ film thickness and 5.0 mm ${ imes}$ 5.0 mm cell area) under 100 mW/$cm^2$ of simulated sunlight.