Direct Numerical Simulation(DNS) of turbulent mass transfer in fully developed turbulent pipe flow has been performed to study the effect of wall boundary conditions on the concentration fields at $Re_{ au}$=180 based on friction velocity and pipe radius. Fully developed turbulent pipe flows for Sc=0.71 are studied with two different wall boundary conditions, namely, constant mass flux and constant wall concentration. The mean concentration profiles and turbulent mass fluxes obtained from the present DNS are in good agreement with the previous numerical results currently available. To investigate the effects of wall boundary condition on the turbulent mass transfer, the mean concentration profile, root-mean-square of concentration fluctuation, turbulent mass fluxes and higher-order statistics(Skewness and Flatness factor) are compared for the two cases. Furthermore, the budgets of turbulent mass fluxes and concentration variance were computed and analyzed to elucidate the effects of wall boundary conditions on the turbulent mass transfer.