The purpose of this study was to investigate the structural relationship among teacher learning community’s climate, teacher efficacy, teacher satisfaction, and teacher burnout using the third year data of Busan Education Longitudinal Study(BELS). In addition, multi-group analysis was conducted to find out differences in structural relationship depending on teachers’ participation in a policy-operated professional learning community . The results of structural equation model analysis were as follows. First, teacher learning community’s climate had a significant effect on both teacher efficacy and job satisfaction. Second, teacher satisfaction and teacher efficacy were found to significantly mediate the effect of teacher learning community’s climate on teacher burnout. Third, Teacher efficacy was found to have an indirect effect on teacher burnout mediated by teacher satisfaction. Fourth, there was no significant difference in the structural relationship between the professional learning community participating group and the non-participating group. Based on these results, the policy suggestions presented in this study are as follows. First, teacher learning community needs to be emphasized on teachers professional development as well as emotional bonds. Second, the in-schools teacher learning community can be a policy alternative to complement the limitations of out-of-school facilities and programs provided for teachers emotional support and exhaustion. Third, the professional learning community policy should not be mandatory and formally operated. Professional learning communities should be voluntary involvement of teachers and routine research activities. In addition, the teacher learning community should be supported to develop as a sustainable organizational culture, rather than as a temporary policy tool.